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Novel aromatic heteromonocyclic-substituted 1,3-cycloalkanediones, enol ester derivatives and salts thereof, exhibit herbicidal activity against a variety of broadleaf and grassy weeds. Certain 2-(2-pyrazinyl) 1,3-cycloalkanediones and their enol esters were also found to be active as mite adulticides and ovicides.

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Reference:
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis—I. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis